Dynamic kinetic resolution in the microbial reduction of alpha-monosubstituted beta-oxoesters: The reduction of 2-carbethoxy-cycloheptanone and 2-carbethoxy-cyclooctanone

被引：23

作者：

Danchet, S ^{[1
]}

Bigot, C ^{[1
]}

Buisson, D ^{[1
]}

Azerad, R ^{[1
]}

机构：

[1] UNIV PARIS 05,CHIM & BIOCHIM PHARMACOL & TOXICOL LAB,CNRS,URA 400,F-75270 PARIS 06,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 11期

关键词：

D O I：

10.1016/S0957-4166(97)00171-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The microbial reduction of the title compounds by various yeasts or filamentous fungi strains affords the corresponding (1S,2R)- and/or (1S,2S)-hydroxyesters in good yield and ee. The determination of their absolute configuration was achieved by transformation into known 2-methylcycloalkanone stereoisomers. (C) 1997 Elsevier Science Ltd.

引用

页码：1735 / 1739

页数：5

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