Conversion of prelaureatin into laurallene, a bromo-allene compound, by enzymatic and chemical bromo-etherification reactions

被引：58

作者：

Ishihara, J ^{[1
]}

Shimada, Y ^{[1
]}

Kanoh, N ^{[1
]}

Takasugi, Y ^{[1
]}

Fukuzawa, A ^{[1
]}

Murai, A ^{[1
]}

机构：

[1] HOKKAIDO UNIV,GRAD SCH SCI,DIV CHEM,SAPPORO,HOKKAIDO 060,JAPAN

来源：

TETRAHEDRON | 1997年 / 53卷 / 25期

关键词：

D O I：

10.1016/S0040-4020(97)00542-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Studies on biomimetic conversion of prelaureatin into laurallene were reported. This unique bromo-allene compound has been assumed to be biogenetically synthesized by bromo-cationic reaction of prelaureatin, an eight-membered ether, containing an enyne unit. The electrophilic bromination afforded laurallene chemically and enzymatically. (C) 1997 Elsevier Science Ltd.

引用

页码：8371 / 8382

页数：12

共 27 条

[11] ENZYMATIC-REACTION OF (3E,6S,7S)-LAUREDIOL AND THE MOLECULAR MODELING STUDIES ON THE CYCLIZATION OF LAUREDIOLS [J].