Synthesis and coordination chemistry of 3a,7a-azaborindenyl, a new isoelectronic analogue of the indenyl ligand

被引:35
作者
Ashe, AJ [1 ]
Yang, H [1 ]
Fang, XD [1 ]
Kampf, JW [1 ]
机构
[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
关键词
D O I
10.1021/om0204944
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The fused-ring diheteroaromatic 3a,7a-azaborindenyl anion (1) has been prepared by a synthesis using the Grubbs ring-closing metathesis. 1 has been converted to the Cp*ZrCl2 complex 2, which closely resembles the corresponding (Ind)Cp*ZrCl2.
引用
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页码:4578 / 4580
页数:3
相关论文
共 42 条
[1]  
[Anonymous], ZIEGLER CATALYSTS
[2]   Synthesis of 1,2-dihydro-1,2-azaborines and their conversion to tricarbonyl chromium and molybdenum complexes [J].
Ashe, AJ ;
Fang, XD ;
Fang, XG ;
Kampf, JW .
ORGANOMETALLICS, 2001, 20 (25) :5413-5418
[3]   A synthesis of aromatic five- and six-membered B-N heterocycles via ring closing metathesis [J].
Ashe, AJ ;
Fang, XD .
ORGANIC LETTERS, 2000, 2 (14) :2089-2091
[4]   1,2-thiaborolide:: A new heteroaromatic π-ligand containing boron and sulfur [J].
Ashe, AJ ;
Fang, XD ;
Kampf, JW .
ORGANOMETALLICS, 2000, 19 (24) :4935-4937
[5]   METALLOCENES - CUSTOMIZED TOOLS FOR PREPARATION OF OLEFINS [J].
AULBACH, M ;
KUBER, F .
CHEMIE IN UNSERER ZEIT, 1994, 28 (04) :197-208
[6]   (Phenylboratabenzene)zirconium complexes: Tuning the reactivity of an olefin polymerization catalyst [J].
Bazan, GC ;
Rodriguez, G ;
Ashe, AJ ;
AlAhmad, S ;
Kampf, JW .
ORGANOMETALLICS, 1997, 16 (12) :2492-2494
[7]   Aminoboratabenzene derivatives of zirconium: A new class of olefin polymerization catalysts [J].
Bazan, GC ;
Rodriguez, G ;
Ashe, AJ ;
AlAhmad, S ;
Muller, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (09) :2291-2292
[8]   STEREOSPECIFIC OLEFIN POLYMERIZATION WITH CHIRAL METALLOCENE CATALYSTS [J].
BRINTZINGER, HH ;
FISCHER, D ;
MULHAUPT, R ;
RIEGER, B ;
WAYMOUTH, RM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (11) :1143-1170
[9]  
COATES GW, 1995, COMPREHENSIVE ORGANO, V12, P1193
[10]   NEW HETEROAROMATIC COMPOUNDS .32. PROPERTIES OF 10,9-BORAZARONAPHTHALENE AND 9-AZA-10-BORADECALIN [J].
DAVIS, FA ;
DEWAR, MJS ;
JONES, R ;
WORLEY, SD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (08) :2094-&