Sputtered thin films of CuBr for ammonia microsensors: morphology, composition and ageing

被引:33
作者
Bendahan, M [1 ]
Lauque, P [1 ]
Lambert-Mauriat, C [1 ]
Carchano, H [1 ]
Seguin, JL [1 ]
机构
[1] Fac Sci & Tech St Jerome, CNRS, UMR 6137, Serv 152,L2MP,Lab Mat & Microelect Provence, F-13397 Marseille 20, France
关键词
gas sensor; ammonia; copper bromide; thin film; sputtering;
D O I
10.1016/S0925-4005(02)00004-7
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Sensitive and selective ammonia sensors were realised by sputter depositing a CuBr film on copper interdigitated electrodes. The effect of the self bias voltage on the composition and morphology of the films was analysed. Films deposited with a self bias voltage above 400 V are well adapted to sensor application since they show a large specific area. Ageing of the films is related to copper diffusion from the electrodes into an originally sub-stoichiometric Cu1-xBr film. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:6 / 11
页数:6
相关论文
共 8 条
[1]   NiTi shape memory alloy thin films: Composition control using optical emission spectroscopy [J].
Bendahan, M ;
Seguin, JL ;
Canet, P ;
Carchano, H .
THIN SOLID FILMS, 1996, 283 (1-2) :61-66
[2]  
COTTON FA, 1962, ADV INORG CHEM, P750
[3]   SPUTTERING THEORY [J].
FALCONE, G .
RIVISTA DEL NUOVO CIMENTO, 1990, 13 (01) :1-52
[4]  
Gopel W., 1996, SENSORS UPDATE SENSO, V13, P49, DOI DOI 10.1002/1616-8984(199607)1:1
[5]  
KUDO T, 1990, SOLID STATE IONICS, P33
[6]  
Maissel L., 1970, HDB THIN FILMS TECHN
[7]  
Sigmund P., 1981, Sputtering by particle bombardment I. Physical sputtering of single-element solids, P9
[8]   HIGH-RATE THICK-FILM GROWTH [J].
THORNTON, JA .
ANNUAL REVIEW OF MATERIALS SCIENCE, 1977, 7 :239-260