Synthesis and spectroscopic characterisation of all the intermediates in the Pd-catalysed methoxycarbonylation of ethene

被引:116
作者
Eastham, GR
Heaton, BT [1 ]
Iggo, JA
Tooze, RP
Whyman, R
Zacchini, S
机构
[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
[2] Ineos Acryl, Middlesbrough TS90 8JE, Cleveland, England
关键词
D O I
10.1039/b001110j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The pathway of the palladium catalysed methoxycarbonylation of ethene to methyl propanoate has been shown to occur via a hydride rather than a methoxycarbonyl cycle and all the intermediates in this cycle have been unambiguously identified by multinuclear NMR spectroscopy and C-13-labelling.
引用
收藏
页码:609 / 610
页数:2
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