The first route to large pore metal phosphonates

被引:122
作者
Groves, John A.
Miller, Stuart R.
Warrender, Stewart J.
Mellot-Draznieks, Caroline
Lightfoot, Philip
Wright, Paul A.
机构
[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[2] UCL Royal Inst Great Britain, Davy Faraday Labs, London W1X 4BS, England
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1039/b605400e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first large pore ( free diameter >7 angstrom) metal phosphonates have been prepared as divalent metal N,N'-piperazinebis( methylenephosphonate)s that possess pores greater than ca. 10 angstrom in free diameter, are stable up to 400 degrees C and offer a route to chiral adsorbents and catalysts.
引用
收藏
页码:3305 / 3307
页数:3
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