Stereochemical activity of the metal-centered lone electron pair in group 14 metallocenes.: Crystal structure of the linear sandwich complex [Cs(iPr)3H2]2Pb

被引：12

作者：

Burkey, DJ

Hanusa, TP

Huffman, JC

机构：

[1] Vanderbilt Univ, Dept Chem, Nashville, TN 37235 USA

[2] Indiana Univ, Ctr Mol Struct, Dept Chem, Bloomington, IN 47405 USA

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 01期

关键词：

D O I：

10.1021/ic9905401

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stereochemically active valence electrons are not present in the structure of [C5Pr(i))3H2]2Pb, which, like [C5Me4(SiMe2Bu(t))]2Pb, possesses parallel cyclopentadienyl rings. There are no close intramolecular contacts that force the rings to be parallel; the structure is consistent with the lack of a strong electronic preference for bending in heavy group 14 metallocenes.

引用

页码：153 / 155

页数：3

共 38 条

[11]

BURKEY DJ, 1994, ADV MATER OPT ELECTR, V4, P1

[12] Synthesis, characterization, and molecular structure of bis{(tert-butyldimethylsilyl)-tetramethylcyclopentadienyl}lead [J].