Electronic devices from electrodeposited metal nanowires

Based on their electronic conductivity behavior, metallic nanowires may have electronic applications ranging from interconnects to sensors. We have recently developed an electrochemical method for synthesizing metal nanowires (Pd, Cd, Mo, Au, Ag, Cu,...) ranging in diameter from a few tens of nanometer to 1 mum with millimeter lengths. These nanowires are prepared by the electrodeposition of metal at step edges present on a graphite surface. These nanowires can be used to connect metal nanoparticles (Ni, Au...) or, once transferred in a polymer cast, can operate as sensors. In this paper, we shall describe the general method of preparation of such naked and beaded nanowires as well as how may these nanowires be manipulated to make electronic devices. As an example of such nanodevice, a brief overview of the characteristics of the first nanowire-based sensor for hydrogen gas (H-2) will be given. (C) 2002 Elsevier Science B.V. All rights reserved.