A versatile ruthenium precursor for biphasic catalysis and its application in ionic liquid biphasic transfer hydrogenation: Conventional vs task-specific catalysts

被引：186

作者：

Geldbach, TJ ^{[1
]}

Dyson, PJ ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, BCH, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 26期

关键词：

D O I：

10.1021/ja048886k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of a novel imidazolium-tagged ruthenium complex, which represents a versatile precursor for aqueous and ionic liquid biphasic catalysis, is reported. Its utility is demonstrated in the highly enantioselective ionic liquid biphasic transfer hydrogenation of acetophenone and is compared to conventional (untagged) complexes. Copyright © 2004 American Chemical Society.

引用

页码：8114 / 8115

页数：2

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