Applications of stoichiometric organotransition metal complexes in organic synthesis

被引:18
作者
Comely, AC [1 ]
Gibson, SE [1 ]
Sur, S [1 ]
机构
[1] Kings Coll London, Dept Chem, London WC2R 2LS, England
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2000年 / Royal Society of Chemistry卷 / 02期
关键词
D O I
10.1039/a903026c
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Applications of stoichiometric organotransition metal complexes in organic synthesis were discussed. Emphasis was placed on new reactivity and methods of use to the practising organic chemist. The reaction of the 'unmasked' acyl anions with organic halides under palladium catalysis was investigated. The use of organotitaniums in organic synthesis also continued to grow.
引用
收藏
页码:109 / 124
页数:16
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共 94 条
[51]  
Kündig EP, 1998, ANGEW CHEM INT EDIT, V37, P3146, DOI 10.1002/(SICI)1521-3773(19981204)37:22<3146::AID-ANIE3146>3.0.CO
[52]  
2-M
[53]   Double diastereodifferentiation in the Mukaiyama aldol reactions of π-allyltricarbonyliron lactone complexes:: 1,7- vs. 1,2-asymmetric induction [J].
Ley, SV ;
Cox, LR ;
Worrall, JM .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (20) :3349-3354
[54]   A new route to functionalised π-allyltricarbonyliron lactam complexes from aziridines and their use in stereoselective synthesis and oxidative conversion to β-lactams [J].
Ley, SV ;
Middleton, B .
CHEMICAL COMMUNICATIONS, 1998, (18) :1995-1996
[55]   Intramolecular cycloadditions between cyclobutadiene and dienes [J].
Limanto, J ;
Snapper, ML .
JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (19) :6440-6441
[56]   Synthesis of mexiletine stereoisomers and related compounds via SNAr nucleophilic substitution of a Cr(CO)3-complexed aromatic fluoride [J].
Loughhead, DG ;
Flippin, LA ;
Weikert, RJ .
JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (09) :3373-3375
[57]   Synthesis of polymer-bound Fischer chromium alkoxy and aminocarbene complexes [J].
Maiorana, S ;
Seneci, P ;
Rossi, T ;
Baldoli, C ;
Ciraco, M ;
de Magistris, E ;
Licandro, E ;
Papagni, A ;
Provera, S .
TETRAHEDRON LETTERS, 1999, 40 (18) :3635-3638
[58]   Oxidation by molecular oxygen: One-pot synthesis of diaryl ketones complexed to tricarbonylchromium [J].
Mandal, SK ;
Sarkar, A .
JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (16) :5672-5674
[59]   A new and extremely efficient, general strategy for the synthesis of enantiomerically pure iridoid aglycones [J].
Marco-Contelles, J ;
Ruiz, J .
TETRAHEDRON LETTERS, 1998, 39 (35) :6393-6394
[60]   An efficient method for conversion of 1-alken-3-yl carbonates to 1-alkenes and 3-chloro-1-alkenes via allyltitaniums [J].
Matsuda, S ;
An, DK ;
Okamoto, S ;
Sato, F .
TETRAHEDRON LETTERS, 1998, 39 (41) :7513-7516