Absorption of H2S andCO2 in alkanolamine aqueous solution:: Experimental data and modelling with the electrolyte-NRTL model

被引：32

作者：

Barreau, A.

le Bouhelec, E. Blanchon

Tounsi, K. N. Habchi

Mougin, P.

Lecomte, F.

机构：

[1] Inst Francais Petr, F-92852 Rueil Malmaison, France

[2] Total, DGEP SCR ED ECP, F-92078 Paris, France

来源：

OIL & GAS SCIENCE AND TECHNOLOGY-REVUE D IFP ENERGIES NOUVELLES | 2006年 / 61卷 / 03期

关键词：

D O I：

10.2516/ogst:2006038a

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

In this work, we are interested in acid gas (H2S and CO2) removal by aqueous solutions of alkanolamine. The first part of the article deals with the development of the experimental apparatus used to determine the partial acid gas pressure as a function of acid gas loading in the reactive liquid phase with the synthetic method. New measurements on water + diethanolamine + CO2 and water + diethanolamine + H2S systems were performed. The second part concerns the modelling of such data. The model used couples the chemical reactions in liquid phase with the phase equilibrium. We use the electrolyte NRTL model for the liquid phase and the Peng and Robinson equation of state to describe the vapour phase. The parameters of the electrolyte NRTL model are determined on experimental acid gas partial pressure data of the studied systems.

引用

页码：345 / 361

页数：17

共 50 条

[1]

Abdi MA, 1999, IND ENG CHEM RES, V38, P3096

[2] Densities of water plus diethanolamine plus methanol and water plus N-methyldiethanolamine methanol at temperatures ranging from (283.15 to 353.15) K [J].