Pulsed laser deposition of CNx films:: role of r.f. nitrogen plasma activation for the film structure formation

被引:6
作者
Bulir, J
Novotny, M
Jelínek, M
Lancok, J
Zelinger, Z
Trchová, M
机构
[1] Acad Sci Czech Republ, Inst Phys, Prague 18221 8, Czech Republic
[2] Acad Sci Czech Republ, Inst Phys Chem, Prague 18223 8, Czech Republic
[3] Charles Univ Prague, Dept Macromol Phys, Fac Math & Phys, CR-18000 Prague 8, Czech Republic
关键词
laser; spectroscopy; radio frequency (r.f.); C3N4;
D O I
10.1016/S0925-9635(01)00587-8
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Thin CNx films were deposited by pulsed laser deposition (PLD) equipped with KrF excimer laser. An additional radio-frequency discharge of the nitrogen gas was applied. The role of atomic nitrogen in CN radical formation was studied using optical emission spectroscopy (OES). The composition of the films was measured by WDX. The N/C ratio of all films was approximately 1 and did not vary greatly with nitrogen pressure. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:1223 / 1226
页数:4
相关论文
共 20 条
[1]   Optical emission diagnostic of laser-induced plasma during CNx film deposition [J].
Aldea, E ;
Caricato, AP ;
Dinescu, G ;
Luches, A ;
Perrone, A .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1997, 36 (7B) :4686-4689
[2]   Study of nitrogen pressure effect on the laser-deposited amorphous carbon films [J].
Bulir, J ;
Jelinek, M ;
Vorlicek, V ;
Zemek, J ;
Perina, V .
THIN SOLID FILMS, 1997, 292 (1-2) :318-323
[3]   Preparation of nitrogen-rich CNx films with inductively coupled plasma CVD and pulsed laser deposition [J].
Bulir, J ;
Delplancke-Ogletree, MP ;
Lancok, J ;
Jelínek, M ;
Popov, C ;
Klett, A ;
Kulisch, W .
DIAMOND AND RELATED MATERIALS, 2001, 10 (9-10) :1901-1909
[4]  
BULIR J, 1999, TMS ANN M SAN DIEG 2, V1, P395
[5]   Deposition of C-N films by reactive laser ablation [J].
DAnna, E ;
Luches, A ;
Perrone, A ;
Acquaviva, S ;
Alexandrescu, R ;
Mihailescu, IN ;
Zemek, J ;
Majni, G .
APPLIED SURFACE SCIENCE, 1996, 106 :126-131
[6]   Optical emission spectroscopy of molecular species in plasma induced by laser ablation of carbon in nitrogen [J].
Dinescu, G ;
Aldea, E ;
De Giorgi, ML ;
Luches, A ;
Perrone, A ;
Zocco, A .
APPLIED SURFACE SCIENCE, 1998, 127 :697-702
[7]   Properties and preparation conditions of carbon nitride thin films deposited by laser CVD [J].
Falk, F ;
Meinschien, J ;
Schuster, K ;
Stafast, H .
CARBON, 1998, 36 (5-6) :765-769
[8]   Synthesis of carbon nitride films at low temperature [J].
Hammer, P ;
Baker, MA ;
Lenardi, C ;
Gissler, W .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1997, 15 (01) :107-112
[9]   Nitrogen-driven sp3 to sp2 transformation in carbon nitride materials [J].
Hu, JT ;
Yang, PD ;
Lieber, CM .
PHYSICAL REVIEW B, 1998, 57 (06) :R3185-R3188
[10]   CNx films created by combined laser deposition and r.f. discharge:: XPS, FTIR and Raman analysis [J].
Jelínek, M ;
Zemek, J ;
Trchová, M ;
Vorlícek, V ;
Lancok, J ;
Tomov, R ;
Simecková, M .
THIN SOLID FILMS, 2000, 366 (1-2) :69-76