Metathesis route to bridged metallocenes

被引：70

作者：

Ogasawara, M ^{[1
]}

Nagano, T ^{[1
]}

Hayashi, T ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 31期

关键词：

D O I：

10.1021/ja026401r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A variety of bridged metallocenes of Fe(II), Ru(II), Zr(IV), or Hf(IV) were prepared in good yield by the interannular ring-closing metathesis reaction of 1,1′-diallylmetallocenes using the Ru-carbene catalyst, and the present method was extended to diastereoselective reaction to give dl- or meso-bridged metallocenes with excellent stereoselectivity. Copyright © 2002 American Chemical Society.

引用

页码：9068 / 9069

页数：2

共 20 条

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