Thiol end-capped one-dimensional platinum and palladium complexes

被引:9
作者
Taher, Deeb
Walfort, Bernhard
Van Koten, Gerard
Lang, Heinrich
机构
[1] Tech Univ Chemnitz, Fak Nat Wissensch, Inst Chem, Lehrstuhl Anorgan Chem, D-09111 Chemnitz, Germany
[2] Univ Utrecht, Debye Inst, NL-3584 CH Utrecht, Netherlands
关键词
D O I
10.1016/j.inoche.2005.10.036
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis and characterisation of acyl-thiol end-capped homobimetallic rigid-rod structured molecules of type [(MeC(O)S-4-NCN)Pt <- N=C-C6H4-C=N -> Pt(NCN-4-SC(O)Me)](OTf)(2) (6, NCN = [C6H2(CH2NMe2-2,6)(2)](-)) and (MeC(O)S-4-C6H4-C6H4)(Ph3P)(2)Pd <- C5H4N-CH=CH-C6H4-CH=CH-C5H4N -> Pd(PPh3)(2)(C6H4-C6H4-4-SC(O)Me)](OTf)(2) (9) in which the metal fragments are spanned by pi-conjugated organic connecting units is reported. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:955 / 958
页数:4
相关论文
共 70 条
[1]  
ALANBER M, 2005, J CHEM SOC DA, P3632
[2]   The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].
Allen, FH .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388
[3]  
[Anonymous], 1994, REDOX MECH INORGANIC
[4]   From organotransition-metal chemistry toward molecular electronics: Electronic communication between ligand-bridged metals [J].
Astruc, D .
ACCOUNTS OF CHEMICAL RESEARCH, 1997, 30 (09) :383-391
[5]  
Aviram A., 1998, Molecular Electronics - Science and Technology
[6]  
Back S, 2000, EUR J INORG CHEM, P1457
[7]   Bis-ortho-chelated diaminoaryl platinum compounds with σ-acetylene substituents.: Investigations into their stability and subsequent construction of multimetallic systems.: The crystal structure of [(μ2-[(η2-NCN)Pt(η1-CO)CCSiMe3])Co2(CO)6] (NCN=2,6-bis[(dimethylamino)methyl]phenyl) [J].
Back, S ;
Gossage, RA ;
Lutz, M ;
del Río, I ;
Spek, AL ;
Lang, H ;
van Koten, G .
ORGANOMETALLICS, 2000, 19 (17) :3296-3304
[8]   Are single molecular wires conducting? [J].
Bumm, LA ;
Arnold, JJ ;
Cygan, MT ;
Dunbar, TD ;
Burgin, TP ;
Jones, L ;
Allara, DL ;
Tour, JM ;
Weiss, PS .
SCIENCE, 1996, 271 (5256) :1705-1707
[9]   Organometallic ''carbon chains'': They just keep getting longer! [J].
Bunz, UHF .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (09) :969-971
[10]  
Cámpora J, 1999, ANGEW CHEM INT EDIT, V38, P147, DOI 10.1002/(SICI)1521-3773(19990115)38:1/2<147::AID-ANIE147>3.3.CO