Thiol end-capped one-dimensional platinum and palladium complexes

被引：9

作者：

Taher, Deeb

Walfort, Bernhard

Van Koten, Gerard

Lang, Heinrich

机构：

[1] Tech Univ Chemnitz, Fak Nat Wissensch, Inst Chem, Lehrstuhl Anorgan Chem, D-09111 Chemnitz, Germany

[2] Univ Utrecht, Debye Inst, NL-3584 CH Utrecht, Netherlands

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 09期

关键词：

D O I：

10.1016/j.inoche.2005.10.036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterisation of acyl-thiol end-capped homobimetallic rigid-rod structured molecules of type [(MeC(O)S-4-NCN)Pt <- N=C-C6H4-C=N -> Pt(NCN-4-SC(O)Me)](OTf)(2) (6, NCN = [C6H2(CH2NMe2-2,6)(2)](-)) and (MeC(O)S-4-C6H4-C6H4)(Ph3P)(2)Pd <- C5H4N-CH=CH-C6H4-CH=CH-C5H4N -> Pd(PPh3)(2)(C6H4-C6H4-4-SC(O)Me)](OTf)(2) (9) in which the metal fragments are spanned by pi-conjugated organic connecting units is reported. (C) 2006 Elsevier B.V. All rights reserved.

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页码：955 / 958

页数：4

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