Thiol end-capped one-dimensional platinum and palladium complexes

被引:9
作者
Taher, Deeb
Walfort, Bernhard
Van Koten, Gerard
Lang, Heinrich
机构
[1] Tech Univ Chemnitz, Fak Nat Wissensch, Inst Chem, Lehrstuhl Anorgan Chem, D-09111 Chemnitz, Germany
[2] Univ Utrecht, Debye Inst, NL-3584 CH Utrecht, Netherlands
关键词
D O I
10.1016/j.inoche.2005.10.036
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis and characterisation of acyl-thiol end-capped homobimetallic rigid-rod structured molecules of type [(MeC(O)S-4-NCN)Pt <- N=C-C6H4-C=N -> Pt(NCN-4-SC(O)Me)](OTf)(2) (6, NCN = [C6H2(CH2NMe2-2,6)(2)](-)) and (MeC(O)S-4-C6H4-C6H4)(Ph3P)(2)Pd <- C5H4N-CH=CH-C6H4-CH=CH-C5H4N -> Pd(PPh3)(2)(C6H4-C6H4-4-SC(O)Me)](OTf)(2) (9) in which the metal fragments are spanned by pi-conjugated organic connecting units is reported. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:955 / 958
页数:4
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