Switching a molecular shuttle on and off: simple, pH-controlled pseudorotaxanes based on cucurbit[7]uril

被引:129
作者
Sindelar, Vladimir
Silvi, Serena
Kaifer, Angel E. [1 ]
机构
[1] Univ Miami, Ctr Supramol Sci, Coral Gables, FL 33124 USA
[2] Univ Miami, Dept Chem, Coral Gables, FL 33124 USA
关键词
D O I
10.1039/b601959e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cucurbit[7[uril, the wheel component in two new and structurally simple pseudorotaxanes, shuttles between the two axle termini at low pH, whereas the shuttling motion stops at higher pH, as the wheel is bound to the center of the axle.
引用
收藏
页码:2185 / 2187
页数:3
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