Synthetic and magnetic studies of a dodecanuclear cobalt wheel

被引:99
作者
Brechin, EK
Cador, O
Caneschi, A
Cadiou, C
Harris, SG
Parsons, S
Vonci, M
Winpenny, REP
机构
[1] Univ Florence, Dipartimento Chim, Lab Magnetismo Mol, Polo Sci Univ, I-50019 Sesto Fiorentino, Italy
[2] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
[3] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
关键词
D O I
10.1039/b205721m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis, structural characterisation and preliminary magnetic studies of a Co-12 wheel are reported; the magnetic investigations reveal that the electronic ground state has a spin S = 6, which corresponds to ferromagnetic interactions between the twelve Co(II) ions.
引用
收藏
页码:1860 / 1861
页数:2
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