Inverse spinel NiFeAlO4 as a highly active oxygen evolution electrocatalyst: promotion of activity by a redox-inert metal ion

被引：166

作者：

Chen, Jamie Y. C. ^{[1
]}

Miller, Jeffrey T. ^{[2
]}

Gerken, James B. ^{[1
]}

Stahl, Shannon S. ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

[2] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2014年 / 7卷 / 04期

关键词：

WATER OXIDATION; NICKEL FERRITE; COMBINATORIAL DISCOVERY; OXIDE CATALYSTS; LOW-TEMPERATURE; PHOTOSYSTEM-II; IRON; O-2; ELECTRODES; HYDROXIDE;

D O I：

10.1039/c3ee43811b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ni:Fe:Al mixed oxides were identified as highly active water oxidation electrocatalysts. A systematic investigation of these materials has led to the characterization of a well-defined NiFeAlO4 inverse spinel catalyst. Electrochemical characterization of NiFeAlO4 shows activity exceeding previously reported catalysts of similar composition and/or structure, including NiO, NiFe (9 : 1), and NiFe2O4.

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页码：1382 / 1386

页数：5

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