Synthesis and structure of a boron cation supported by a β-diketiminate ligand

被引：34

作者：

Cowley, AH ^{[1
]}

Lu, Z ^{[1
]}

Jones, JN ^{[1
]}

Moore, JA ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 15期

关键词：

boron; cation; diketiminate; X-ray; DFT calculation;

D O I：

10.1016/j.jorganchem.2004.05.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The salt [HC(CMe)(2)(NAr)(2)BPh][Al2Cl7] (3); Ar = 2,6i-Pr2C6H3) has been synthesized via the in situ preparation of [HC(CMe)(2) (NAr)(2)BClPh], followed by treatment with A1Cl(3). X-ray analysis of 3 reveals that the BN2C3 ring of the boron cation is planar and DFT calculations indicate pi-type interactions in the HOMO-6 and HOMO-7 orbitals. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：2562 / 2564

页数：3

共 10 条

[1] The chemistry of β-diketiminatometal complexes [J].