Polycyclic aromatic sulfur heterocycles as information carriers in environmental studies

被引:62
作者
Andersson, Jan T.
Hegazi, Abdelrahman H.
Roberz, Benedikte
机构
[1] Univ Munster, Inst Organ & Analyt Chem, D-48149 Munster, Germany
[2] Univ Alexandria, Fac Sci, Dept Chem, Alexandria, Egypt
关键词
sulfur aromatic compounds; PASH; markers; environmental chemistry; separations;
D O I
10.1007/s00216-006-0704-y
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Polycyclic aromatic hydrocarbons (PAHs) play a huge role in environmental analytical chemistry, both as pollutants and as markers for many processes. On the other hand, polycyclic aromatic sulfur heterocycles (PASHs; heterocyclic compounds related to PAHs) have been studied far less intensely, but such studies may lead to a great deal of information not available through the study of PAHs. Here we discuss analytical aspects of PASHs in environmental matrices and their use as information carriers. Since PASHs accompany PAHs in sampling and work-up, it is not necessary to expend much extra analytical effort in order to analyze them. This work reviews how they can provide information on diverse processes such as petroleum, industrial and vehicular pollution, and sources of air and marine pollution.
引用
收藏
页码:891 / 905
页数:15
相关论文
共 89 条
[11]   Are exposure and ecological risks of PAHs underestimated at petroleum contaminated sites? [J].
Barron, MG ;
Holder, E .
HUMAN AND ECOLOGICAL RISK ASSESSMENT, 2003, 9 (06) :1533-1545
[12]   Determination of thiaarenes and polycyclic aromatic hydrocarbons in workplace air of an aluminum reduction plant [J].
Becker, G ;
Colmsjö, A ;
Östman, C .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1999, 33 (09) :1321-1327
[13]   Determination of polycyclic aromatic sulfur heterocyclic compounds in airborne particulate by gas chromatography with atomic emission and mass spectrometric detection [J].
Becker, G ;
Nilsson, U ;
Colmsjö, A ;
Östman, C .
JOURNAL OF CHROMATOGRAPHY A, 1998, 826 (01) :57-66
[14]   Gas chromatography atomic emission detection for quantification of polycyclic aromatic sulfur heterocycles [J].
Becker, G ;
Colmsjö, A .
ANALYTICA CHIMICA ACTA, 1998, 376 (03) :265-272
[15]   REMOVAL OF ELEMENTAL SULFUR FROM HYDROCARBON FRACTIONS [J].
BLUMER, M .
ANALYTICAL CHEMISTRY, 1957, 29 (07) :1039-1041
[16]   Dibenzothiophene in crude oils: Products from the photochemical degradation [J].
Bobinger, S ;
Traulsen, F ;
Andersson, JT .
POLYCYCLIC AROMATIC COMPOUNDS, 1999, 14 :253-263
[17]   Investigation of the sulfur speciation in petroleum products by capillary gas chromatography with ICP-collision cell-MS detection [J].
Bouyssiere, B ;
Leonhard, P ;
Pröfrock, D ;
Baco, F ;
Garcia, CL ;
Wilbur, S ;
Prange, A .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2004, 19 (05) :700-702
[18]   Effect-directed identification of oxygen and sulfur heterocycles as major polycyclic aromatic cytochrome P4501A-Inducers in a contaminated sediment [J].
Brack, W ;
Schirmer, K .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2003, 37 (14) :3062-3070
[19]   Composition and syngeneity of molecular fossils from the 2.78 to 2.45 billion-year-old Mount Bruce Supergroup, Pilbara Craton, Western Australia [J].
Brocks, JJ ;
Buick, R ;
Logan, GA ;
Summons, RE .
GEOCHIMICA ET COSMOCHIMICA ACTA, 2003, 67 (22) :4289-4319
[20]  
CHIRON AS, 2005, CO WEBSITE