Facile synthesis of acidic copolymers via atom transfer radical polymerization in aqueous media at ambient temperature

被引:168
作者
Wang, XS [1 ]
Jackson, RA [1 ]
Armes, SP [1 ]
机构
[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England
关键词
D O I
10.1021/ma991612a
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
An efficient, well-controlled copolymerization of an acidic monomer, sodium 4-vinylbenzoate, via atom transfer radical polymerization in aqueous media was demonstrated. CuIBr and the ligand 2,2′-bipyridine were used as catalysts. The process produced excellent yields in very short reaction times even at 20 °C.
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页码:255 / 257
页数:3
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