Lewis base-catalyzed transformation of α,β-unsaturated aldehydes to saturated carboxylic acids, esters and amides

被引:25
作者
Kawabata, H [1 ]
Hayashi, M [1 ]
机构
[1] Kobe Univ, Fac Sci, Dept Chem, Kobe, Hyogo 6578501, Japan
基金
日本学术振兴会;
关键词
Lewis base; alpha; beta-unsaturated aldehyde; carboxylic acid;
D O I
10.1016/S0040-4039(02)01133-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reactions of alpha,beta-unsaturated aldehydes such as (E)-cinnamaldehyde and 2- or 4-methoxycinnamaldehyde with trimethylsilyl cyanide in the presence of a catalytic amount of a Lewis base such as TTMPP and DBU afforded the corresponding saturated carboxylic acids after hydrolysis. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:5645 / 5647
页数:3
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