共 6 条
Lewis base-catalyzed transformation of α,β-unsaturated aldehydes to saturated carboxylic acids, esters and amides
被引:25
作者:
Kawabata, H
[1
]
Hayashi, M
[1
]
机构:
[1] Kobe Univ, Fac Sci, Dept Chem, Kobe, Hyogo 6578501, Japan
基金:
日本学术振兴会;
关键词:
Lewis base;
alpha;
beta-unsaturated aldehyde;
carboxylic acid;
D O I:
10.1016/S0040-4039(02)01133-4
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
The reactions of alpha,beta-unsaturated aldehydes such as (E)-cinnamaldehyde and 2- or 4-methoxycinnamaldehyde with trimethylsilyl cyanide in the presence of a catalytic amount of a Lewis base such as TTMPP and DBU afforded the corresponding saturated carboxylic acids after hydrolysis. (C) 2002 Elsevier Science Ltd. All rights reserved.
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页码:5645 / 5647
页数:3
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