A trinuclear EMAC-type molecular wire with redox-active ferrocenylacetylide "alligator clips" attached

被引：63

作者：

Berry, JF ^{[1
]}

Cotton, FA ^{[1
]}

Murillo, CA ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, Mol Struct & Bonding Lab, College Stn, TX 77843 USA

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 10期

关键词：

D O I：

10.1021/om049979d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of lithium ferrocenylacetylide (LiFcA) with [CO3(dpa)(4)(NCCH3)(2)](PF6)(2) (dpa = 2,2'-dipyridylamide) in acetonitrile solution yields the bisferrocenylacetylide EMAC (extended metal atom chain) Co-3(dpa)(4)(FcA)(2) in good yield and excellent purity. The crystal structure features a distinctly unsymmetrical tricobalt chain with a Co-Co bond distance of 2.3091(8) Angstrom and a longer Co...Co separation of 2.5208(9) Angstrom. Cyclic and differential pulse voltammetry show that the two Fe-2divided by13divided by oxidations occur nearly simultaneously, with a DeltaE(1/2) of 71 mV.

引用

页码：2503 / 2506

页数：4

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