Fluorous columns are superior to cyclodextrin columns for demixing in fluorous mixture synthesis: When and why to use fluorous silica gel

被引：15

作者：

Curran, DP ^{[1
]}

Dandapani, S ^{[1
]}

Werner, S ^{[1
]}

Matsugi, M ^{[1
]}

机构：

[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA

来源：

SYNLETT | 2004年 / 09期

关键词：

fluorine; cyclodextrin; chromatography; separation technique; fluorous mixture synthesis;

D O I：

10.1055/s-2004-829078

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Measurements of retention times of assorted fluorous and non-fluorous compounds on both fluorous (FluoroFlash PF-C8) and cyclodextrin (Sumichiral OA 7500) columns show that the fluorous column is superior to the cyclodextrin column for separating fluorous compounds. Guidelines for when and why to use fluorous columns are suggested.

引用

收藏

页码：1545 / 1548

页数：4

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