A family of nanoporous materials based on an amino acid backbone

被引：367

作者：

Vaidhyanathan, Ramanathan ^{[1
]}

Bradshaw, Darren ^{[1
]}

Rebilly, Jean-Noel ^{[1
]}

Barrio, Jorge P. ^{[1
]}

Gould, Jamie A. ^{[1
]}

Berry, Neil G. ^{[1
]}

Rosseinsky, Matthew J. ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 39期

基金：

英国工程与自然科学研究理事会;

关键词：

amino acids; chirality; metal-organic frameworks; nanoporous materials; sorption;

D O I：

10.1002/anie.200602242

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) In the pocket: A nanoporous framework with internal surfaces lined with amino acid residues (see structure; Ni cyan, C gray (chiral centers yellow), H white, N blue, O red) is produced by the pillaring of nickel-aspartate layers by 4,4′-bipyridine. The presence of pockets capable of multiple interactions with guest species permits the enantioselective sorption of short-chain diols. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6495 / 6499

页数：5

共 19 条

[1] ASSEMBLY OF PORPHYRIN BUILDING-BLOCKS INTO NETWORK STRUCTURES WITH LARGE CHANNELS
ABRAHAMS, BF
HOSKINS, BF
MICHAIL, DM
ROBSON, R
[J]. NATURE, 1994, 369 (6483) : 727 - 729
[2] [Ni2O(L-Asp)(H2O)2]•4H2O:: A homochiral 1D helical chain hybrid compound with extended Ni-O-Ni bonding
Anokhina, EV
Jacobson, AJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (10) : 3044 - 3045
[3] COORDINATION BEHAVIOR OF L-ASPARTIC ACID - TERNARY NICKEL(II) COMPLEXES WITH IMIDAZOLES - CRYSTAL AND MOLECULAR-STRUCTURE OF (L-ASPARTATE)TRIS(IMIDAZOLE)NICKEL(II)
BATTAGLIA, LP
CORRADI, AB
ANTOLINI, L
MARCOTRIGIANO, G
MENABUE, L
PELLACANI, GC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (09) : 2407 - 2411
[4] Permanent microporosity and enantioselective sorption in a chiral open framework
Bradshaw, D
Prior, TJ
Cussen, EJ
Claridge, JB
Rosseinsky, MJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) : 6106 - 6114
[5] A route to high surface area, porosity and inclusion of large molecules in crystals
Chae, HK
Siberio-Pérez, DY
Kim, J
Go, Y
Eddaoudi, M
Matzger, AJ
O'Keeffe, M
Yaghi, OM
[J]. NATURE, 2004, 427 (6974) : 523 - 527
[6] Dybtesev D.N., 2006, ANGEW CHEM, V118, P930, DOI [DOI 10.1002/ANGE.200503023, 10.1002/ange.200503023]
[7] A homochiral metal-organic material with permanent porosity, enantioselective sorption properties, and catalytic activity
Dybtsev, DN
Nuzhdin, AL
Chun, H
Bryliakov, KP
Talsi, EP
Fedin, VP
Kim, K
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (06) : 916 - 920
[8] A chromium terephthalate-based solid with unusually large pore volumes and surface area
Férey, G
Mellot-Draznieks, C
Serre, C
Millange, F
Dutour, J
Surblé, S
Margiolaki, I
[J]. SCIENCE, 2005, 309 (5743) : 2040 - 2042
[9] The chirality, porosity, and ferromagnetism of a 3D nickel glutarate with intersecting 20-membered ring channels
Guillou, N
Livage, C
Drillon, M
Férey, G
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (43) : 5314 - 5317
[10] Efficient docking of peptides to proteins without prior knowledge of the binding site
Hetényi, C
van der Spoel, D
[J]. PROTEIN SCIENCE, 2002, 11 (07) : 1729 - 1737

← 1 2 →