Synthesis of 2-oxazolidinone from β-aminoalcohol using Supercritical carbon dioxide

被引:20
作者
Kawanami, H
Ikushima, Y
机构
[1] Natl Inst Adv Ind Sci & Technol, Supercrit Res Ctr, Miyagino Ku, Sendai, Miyagi 9838551, Japan
[2] Japan Sci & Technol Corp, CREST, Miyagino Ku, Sendai, Miyagi 9838551, Japan
关键词
2-oxazolidinone; amino alcohol; carbon dioxide; supercritical condition; chemical fixation;
D O I
10.1627/jpi.45.321
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The synthesis Of 2-oxazolidinone from beta-amino alcohol by chemical fixation of carbon dioxide under supercritical conditions using NN'-dicyclohexylcarbodiimide (DCC) was developed. Even though in non-solvent conditions, 2-oxazolidinone was synthesized with a maximum yield of 96.7% at the critical pressure.
引用
收藏
页码:321 / 324
页数:4
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