A Difluorobenzoxadiazole Building Block for Efficient Polymer Solar Cells

被引：130

作者：

Zhao, Jingbo ^{[1
,2
]}

Li, Yunke ^{[1
,2
]}

Hunt, Adrian ^{[3
,4
]}

Zhang, Jianquan ^{[1
,2
,5
]}

Yao, Huatong ^{[1
,2
]}

Li, Zhengke ^{[1
,2
]}

Zhang, Jie

Huang, Fei ^{[5
]}

Ade, Harald ^{[3
,4
]}

Yan, He ^{[1
,2
,6
]}

机构：

[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

[2] Hong Kong Univ Sci & Technol, Energy Inst, Kowloon, Hong Kong, Peoples R China

[3] N Carolina State Univ, Dept Phys, Raleigh, NC 27695 USA

[4] N Carolina State Univ, Organ & Carbon Elect Lab ORaCEL, Raleigh, NC 27695 USA

[5] S China Univ Technol, Inst Polymer Optoelect Mat & Devices, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China

[6] Hong Kong Univ Sci & Technol, Shenzhen Res Inst, 9 Yuexing 1st RD,Hitech Pk, Shenzhen 518057, Peoples R China

来源：

ADVANCED MATERIALS | 2016年 / 28卷 / 09期

基金：

美国国家科学基金会;

关键词：

CONJUGATED POLYMERS; FLUORINATED BENZOTHIADIAZOLE; BANDGAP POLYMER; PERFORMANCE; MORPHOLOGY; COPOLYMER; CONVERSION; AGGREGATION; DERIVATIVES; DESIGN;

D O I：

10.1002/adma.201504611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A difluorobenzoxadiazole building block is synthesized and utilized to construct a conjugated polymer leading to high-performance thick-film polymer solar cells with a VOC of 0.88 V and a power conversion efficiency of 9.4%. This new building block can be used in many possible polymer structures for various organic electronic applications. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

收藏

页码：1868 / 1873

页数：6

相关论文

共 49 条

[21]

He ZC, 2015, NAT PHOTONICS, V9, P174, DOI [10.1038/NPHOTON.2015.6, 10.1038/nphoton.2015.6]

[22] A SAXS/WAXS/GISAXS Beamline with Multilayer Monochromator [J].

Hexemer, Alexander ;

Bras, Wim ;

Glossinger, James ;

Schaible, Eric ;

Gann, Eliot ;

Kirian, Rick ;

MacDowell, Alastair ;

Church, Matthew ;

Rude, Bruce ;

Padmore, Howard .

XIV INTERNATIONAL CONFERENCE ON SMALL-ANGLE SCATTERING (SAS09), 2010, 247

[23] Improved Performance of Polymer Bulk Heterojunction Solar Cells Through the Reduction of Phase Separation via Solvent Additives [J].

Hoven, Corey V. ;

Dang, Xuan-Dung ;

Coffin, Robert C. ;

Peet, Jeff ;

Nguyen, Thuc-Quyen ;

Bazan, Guillermo C. .

ADVANCED MATERIALS, 2010, 22 (08) :E63-+

[24] Single-Junction Organic Solar Cells Based on a Novel Wide-Bandgap Polymer with Efficiency of 9.7% [J].

Huo, Lijun ;

Liu, Tao ;

Sun, Xiaobo ;

Cai, Yunhao ;

Heeger, Alan J. ;

Sun, Yanming .

ADVANCED MATERIALS, 2015, 27 (18) :2938-+

[25] Nika: software for two-dimensional data reduction [J].

Ilavsky, Jan .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2012, 45 :324-328

[26] Revisiting the Synthesis of 4,6-Difluorobenzofuroxan: A Study of Its Reactivity and Access to Fluorinated Quinoxaline Oxides [J].

Jovene, Cyril ;

Jacquet, Morgane ;

Marrot, Jerome ;

Bourdreux, Flavien ;

Kletsky, Mikhail E. ;

Burov, Oleg N. ;

Goncalves, Anne-Marie ;

Goumont, Regis .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2014, 2014 (29) :6451-6466

[27] Well-controlled thieno[3,4-c]pyrrole-4,6-(5H)-dione based conjugated polymers for high performance organic photovoltaic cells with the power conversion efficiency exceeding 9% [J].

Kim, Ji-Hoon ;

Park, Jong Baek ;

Jung, In Hwan ;

Grimsdale, Andrew C. ;

Yoon, Sung Cheol ;

Yang, Hoichang ;

Hwang, Do-Hoon .

ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (08) :2352-2356

[28] Discovery of Chemoselective and Biocompatible Reactions Using a High-Throughput Immunoassay Screening [J].

Kolodych, Sergii ;

Rasolofonjatovo, Evelia ;

Chaumontet, Manon ;

Nevers, Marie-Claire ;

Creminon, Christophe ;

Taran, Frederic .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (46) :12056-12060

[29] Donor-Acceptor Alternating Copolymer Nanowires for Highly Efficient Organic Solar Cells [J].

Lee, Jaewon ;

Jo, Sae Byeok ;

Kim, Min ;

Kim, Heung Gyu ;

Shin, Jisoo ;

Kim, Haena ;

Cho, Kilwon .

ADVANCED MATERIALS, 2014, 26 (39) :6706-6714

[30] Aggregation and morphology control enables multiple cases of high-efficiency polymer solar cells [J].

Liu, Yuhang ;

Zhao, Jingbo ;

Li, Zhengke ;

Mu, Cheng ;

Ma, Wei ;

Hu, Huawei ;

Jiang, Kui ;

Lin, Haoran ;

Ade, Harald ;

Yan, He .

NATURE COMMUNICATIONS, 2014, 5

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