A two-step synthesis of new macrobicyclic aza-ligands starting from ''trans''dioxocyclam as diprotected macrocycle

被引：37

作者：

Denat, F ^{[1
]}

Lacour, S ^{[1
]}

Brandes, S ^{[1
]}

Guilard, R ^{[1
]}

机构：

[1] UNIV BOURGOGNE,LAB INGN MOL SEPARAT & APPLICAT GRAZ,LIMSAG,UMR 5633,F-21000 DIJON,FRANCE

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 25期

关键词：

D O I：

10.1016/S0040-4039(97)00944-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A rapid and convenient synthesis of two small aza-cryptands containing a 1,4,8,11-tetraazacyclotetradecane backbone is reported. This strategy can be applied to the preparation of many other aza-cages by varying the nature of the cross linker. Moreover, the two remaining secondary amine sites may allow the functionalization of these ligands or their grafting on a polymer. (C) 1997 Published by Elsevier Science Ltd.

引用

页码：4417 / 4420

页数：4

共 26 条

[1] DESIGN AND SYNTHESIS OF MACROCYCLIC LIGANDS AND THEIR COMPLEXES OF LANTHANIDES AND ACTINIDES
ALEXANDER, V
[J]. CHEMICAL REVIEWS, 1995, 95 (02) : 273 - 342
[2] Aza-macrocycles bearing lipophilic functions. Their synthesis and selective lithium complexation
Bencini, A
Fusi, V
Giorgi, C
Micheloni, M
Nardi, N
Valtancoli, B
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1996, (11): : 2297 - 2302
[3] SYNTHESIS AND CHARACTERIZATION OF AN AZA-CAGE, BASICITY BEHAVIOR AND CRYSTAL-STRUCTURE OF ITS DIPROTONATED SPECIES
BENCINI, A
BIANCHI, A
BAZZICALUPI, C
CIAMPOLINI, M
DAPPORTO, P
FUSI, V
MICHELONI, M
NARDI, N
PAOLI, P
VALTANCOLI, B
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1993, (04): : 715 - 720
[4] SYNTHESIS AND CHARACTERIZATION OF AN AZA-CAGE BEHAVING AS A PROTON SPONGE - CRYSTAL-STRUCTURES OF ITS MONOPROTONATED AND TRIPROTONATED SPECIES
BENCINI, A
BIANCHI, A
BAZZICALUPI, C
CIAMPOLINI, M
DAPPORTO, P
FUSI, V
MICHELONI, M
NARDI, N
PAOLI, P
VALTANCOLI, B
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1993, (01): : 115 - 120
[5] THERMODYNAMIC ASPECTS OF THE POLYAZACYCLOALKANE COMPLEXES WITH CATIONS AND ANIONS
BIANCHI, A
MICHELONI, M
PAOLETTI, P
[J]. COORDINATION CHEMISTRY REVIEWS, 1991, 110 (01) : 17 - 113
[6] CHARACTERIZATION AND APPLICATION OF A NEW DIPROTECTED CYCLAM - A NOVEL 2-STEP SYNTHESIS OF LINKED TETRAAZAMACROCYCLES
BOITREL, B
ANDRIOLETTI, B
LACHKAR, M
GUILARD, R
[J]. TETRAHEDRON LETTERS, 1995, 36 (28) : 4995 - 4998
[7] Bradshaw J. S., 1993, CHEM HETEROCYCLIC CO, V51, P1
[8] CABANI S, 1996, REACT FUNCT POLYM, P137
[9] SMALL AZA CAGES AS FAST PROTON SPONGES AND STRONG LITHIUM BINDERS
CIAMPOLINI, M
NARDI, N
VALTANCOLI, B
MICHELONI, M
[J]. COORDINATION CHEMISTRY REVIEWS, 1992, 120 : 223 - 236
[10] GUILARD R, 1996, Patent No. 9629363

← 1 2 3 →