Transesterification/acylation reactions catalyzed by molecular catalysts

被引：163

作者：

Grasa, GA

Singh, R

Nolan, SP ^{[1
]}

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

[2] Johnson Matthey Catalysts Chiral Technol, Cambridge CB4 1FP, England

来源：

SYNTHESIS-STUTTGART | 2004年 / 07期

关键词：

transesterifications; acylations; catalysis; carbenes; esters;

D O I：

10.1055/s-2004-822323

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A survey of catalysts able to mediate the transesterification/acylation reaction is presented. Metal and organic catalysts are capable of facilitating this important transformation. 1 Introduction 2 Transesterification Reactions Catalyzed by Lewis Acids 2.1 Lanthanide (Sm) Catalysis 2.2 Tin Catalysis 2.3 Indium Catalysis 2.4 Yttrium Catalysis 3 Transesterification Reactions Catalyzed by Nucleophilic Catalysts 3.1 Superbase-Catalyzed Transesterification of Esters with Alcohols 3.2 Nucleophilic N-Heterocyclic Carbene (NHC) Catalysis 4 Conclusions.

引用

收藏

页码：971 / 985

页数：15

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