Interaction of NO with the MgO(100) surface studied by infrared reflection absorption spectroscopy

被引：15

作者：

Kim, CM ^{[1
]}

Yi, CW ^{[1
]}

Min, BK ^{[1
]}

Santra, AK ^{[1
]}

Goodman, DW ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

LANGMUIR | 2002年 / 18卷 / 15期

关键词：

Infrared reflection absorption spectroscopy (IRAS);

D O I：

10.1021/la020170k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Infrared reflection absorption spectroscopy (IRAS) at low temperatures (ca. 40 K) has been used to study the interaction of NO with highly ordered MgO(100) thin films. Dimer formation has been observed in the multilayer regime at (<60 K) and in the monolayer regime at 60-70 K. Using (NO)-N-15, it is shown that dimeric NO, (NO)(2), is the key intermediate in the formation of N2O above 70 K.

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收藏

页码：5651 / 5652

页数：2

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