Dirhodium tetracarboxylate derived from adamantylglycine as a chiral catalyst for carbenoid reactions

被引：155

作者：

Reddy, Ravisekhara P. ^{[1
]}

Lee, Gene H. ^{[1
]}

Davies, Huw M. L. ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 16期

关键词：

D O I：

10.1021/ol060893l

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The dirhodium tetracarboxylate, Rh-2(S-PTAD)(4), derived from adamantylglycine, is a very effective chiral catalyst for carbenoid reactions. High asymmetric induction was obtained in Rh-2(S-PTAD)(4)-catalyzed intramolecular C-H insertion (94% ee), intermolecular cyclopropanation (99% ee), and intermolecular C-H insertion (92% ee).

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收藏

页码：3437 / 3440

页数：4

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