Intermolecular Se•••Se interactions observed in indium compounds containing dialkyl diselenophosphate ligands:: syntheses, structure, and solution studies of [In{Se2P(OR)2}3] (R = Et, iPr)

被引:14
作者
Chen, JM [1 ]
Santra, BK [1 ]
Liu, CW [1 ]
机构
[1] Chung Yuan Christian Univ, Dept Chem, Pu Chung Li 320, Taiwan
关键词
diselenophosphates; indium; Se center dot center dot center dot Se interactions; supramolecular structure;
D O I
10.1016/j.inoche.2004.08.006
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Weak intermolecular (SeSe)-Se-... interactions exist between adjacent molecules of [In{Se2P((OPr)-Pr-i)(2)}(3)] and form a loosely connected dimer. VT P-31 NMR studies suggest that In-Se bonds are labile in solution. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:1103 / 1105
页数:3
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