Necked ZnO nanoparticle-based NO2 sensors with high and fast response

被引：97

作者：

Jun, Jin Hyung ^{[1
,2
]}

Yun, Junggwon ^{[1
,2
]}

Cho, Kyoungah ^{[1
,2
]}

Hwang, In-Sung ^{[3
]}

Lee, Jong-Heun ^{[3
]}

Kim, Sangsig ^{[1
,2
]}

机构：

[1] Korea Univ, Dept Elect Engn, Seoul 136701, South Korea

[2] Korea Univ, Inst Nano Sci, Seoul 136701, South Korea

[3] Korea Univ, Dept Mat Sci & Engn, Seoul 136701, South Korea

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 2009年 / 140卷 / 02期

关键词：

ZnO nanoparticles; Non-agglomerated necking; Gas sensor; NO2; Response; GAS-SENSING PROPERTIES; NANOCRYSTALLINE ZINC-OXIDE; THIN-FILM; SENSITIVITY; SNO2;

D O I：

10.1016/j.snb.2009.05.019

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The NO2 gas sensing characteristics of semiconductor type gas sensors with channels composed of necked ZnO nanoparticles (NPs) were investigated in this study. The heat treatment of the NPs at 400 degrees C led to their necking and coarsening. The response of the necked-NP-based sensors was as high as 106 when exposed to 0.2 ppm of NO2 at 200 degrees C. As the concentration of NO2 increased to 5 ppm, their response was enhanced to approximately 400. During the repeated injection of NO2 gas with a concentration of 0.4 ppm, the sensors exhibited stable response characteristics. Furthermore, the 90% response and recovery times of the gas sensor were as fast as 13 and 10s, respectively. These observations indicate that the non-agglomerated necking of the NPs induced by the heat treatment significantly enhances the gas sensing characteristics of the NP-based gas sensors. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：412 / 417

页数：6

共 24 条

[1] Low temperature selective NO2 sensors by nanostructured fibres of ZnO [J].

Baratto, C ;

Sberveglieri, G ;

Onischuk, A ;

Caruso, B ;

di Stasio, S .

SENSORS AND ACTUATORS B-CHEMICAL, 2004, 100 (1-2) :261-265

[2] Conduction model of metal oxide gas sensors [J].

Barsan, N ;

Weimar, U .

JOURNAL OF ELECTROCERAMICS, 2001, 7 (03) :143-167

[3] Fast response methane sensor using nanocrystalline zinc oxide thin films derived by sol-gel method [J].

Bhattacharyya, P. ;

Basu, P. K. ;

Saha, H. ;

Basu, S. .

SENSORS AND ACTUATORS B-CHEMICAL, 2007, 124 (01) :62-67

[4] INFLUENCE OF SURFACE PROCESSES ON ELECTRICAL, PHOTOCHEMICAL, AND THERMODYNAMICAL PROPERTIES OF ZINC-OXIDE FILMS [J].

BONASEWICZ, P ;

HIRSCHWALD, W ;

NEUMANN, G .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1986, 133 (11) :2270-2278

[5] ZnO nanoparticulate thin film: preparation, characterization and gas-sensing property [J].

Cheng, XL ;

Zhao, H ;

Huo, LH ;

Gao, S ;

Zhao, JG .

SENSORS AND ACTUATORS B-CHEMICAL, 2004, 102 (02) :248-252

[6] NO2 sensing characteristics of ZnO nanorods prepared by hydrothermal method [J].

Cho, Pyeong-Seok ;

Kim, Ki-Won ;

Lee, Jong-Heun .

JOURNAL OF ELECTROCERAMICS, 2006, 17 (2-4) :975-978

[7] Stable and highly sensitive gas sensors based on semiconducting oxide nanobelts [J].

Comini, E ;

Faglia, G ;

Sberveglieri, G ;

Pan, ZW ;

Wang, ZL .

APPLIED PHYSICS LETTERS, 2002, 81 (10) :1869-1871

[8] Electrostatic spray deposited zinc oxide films for gas sensor applications [J].

Ghimbeu, Camelia Matei ;

Schoonman, Joop ;

Lumbreras, Martine ;

Siadat, Maryam .

APPLIED SURFACE SCIENCE, 2007, 253 (18) :7483-7489

[9]

Hwang IS, 2006, J KOREAN PHYS SOC, V49, P1229

[10] Gas-sensing properties of ordered mesoporous SnO2 and effects of coatings thereof [J].

Hyodo, T ;

Abe, S ;

Shimizu, Y ;

Egashira, M .

SENSORS AND ACTUATORS B-CHEMICAL, 2003, 93 (1-3) :590-600

← 1 2 3 →