Ultrasound: promoting electroanalysis in difficult real world media

被引:37
作者
Banks, CE [1 ]
Compton, RG [1 ]
机构
[1] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England
关键词
D O I
10.1039/b403356f
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This article outlines the recent progress in the field of sonoelectroanalysis with strong emphasis on 'real world media' analysis. General principles of stripping analysis and the effects of ultrasound are explained. A section on 'Electroanalysis in extreme media' presents several examples of applications including detection of copper in beer, manganese in tea, lead and cadmium in saliva. The benefits of diamond electrodes are described and in the final section 'Metal ion detection in blood' several novel approaches based on the use of power ultrasound and based on bismuth electrodes are discussed. Specifically it is shown that the combination of ultrasound with classical stripping voltammetry permits quantifiable measurements in media hitherto impossible to study using conventional methods.
引用
收藏
页码:678 / 683
页数:6
相关论文
共 29 条
  • [1] Anodic stripping voltammetry of copper at insonated glassy carbon-based electrodes:: application to the determination of copper in beer
    Agra-Gutiérrez, C
    Hardcastle, JL
    Ball, JC
    Compton, RG
    [J]. ANALYST, 1999, 124 (07) : 1053 - 1057
  • [2] Sono-electroanalysis: Application to the detection of lead in wine
    Akkermans, RP
    Ball, JC
    Rebbitt, TO
    Marken, F
    Compton, RG
    [J]. ELECTROCHIMICA ACTA, 1998, 43 (23) : 3443 - 3449
  • [3] Cadmium detection via boron-doped diamond electrodes:: surfactant inhibited stripping voltarnmetry
    Banks, CE
    Hyde, ME
    Tomcík, P
    Jacobs, R
    Compton, RG
    [J]. TALANTA, 2004, 62 (02) : 279 - 286
  • [4] Blythe AN, 2000, ELECTROANAL, V12, P16, DOI 10.1002/(SICI)1521-4109(20000101)12:1<16::AID-ELAN16>3.0.CO
  • [5] 2-Z
  • [6] Brett AMO, 1997, ULTRASON SONOCHEM, V4, P123
  • [7] Poly(ester sulphonic acid) coated mercury thin film electrodes: characterization and application in batch injection analysis stripping voltammetry of heavy metal ions
    Brett, CMA
    Fungaro, DA
    [J]. TALANTA, 2000, 50 (06) : 1223 - 1231
  • [8] Novel polymer-modified electrodes for batch injection sensors and application to environmental analysis
    Brett, CMA
    Fungaro, DA
    Morgado, JM
    Gil, MH
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 468 (01): : 26 - 33
  • [9] Electroanalysis at diamond-like and doped-diamond electrodes
    Compton, RG
    Foord, JS
    Marken, F
    [J]. ELECTROANALYSIS, 2003, 15 (17) : 1349 - 1363
  • [10] Voltammetry in the presence of ultrasound: Mass transport effects
    Compton, RG
    Eklund, JC
    Page, SD
    Mason, TJ
    Walton, DJ
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1996, 26 (08) : 775 - 784