Rapid ring-opening polymerization of D,L-lactide by microwaves

被引：46

作者：

Zhang, C ^{[1
]}

Liao, LQ ^{[1
]}

Liu, LJ ^{[1
]}

机构：

[1] Wuhan Univ, Minist Educ, Key Lab Biomed Polymers, Coll Chem & Mol Sci,Dept Polymer Sci, Wuhan 430072, Peoples R China

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 15期

关键词：

degradation; D; L-lactide; microwave; ring-opening polymerization;

D O I：

10.1002/marc.200400106

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly((D,L)-lactide) with a molar mass of 105 g. mol(-1) and a yield over 90% was produced in 10 min by the ring-opening polymerization Of (D,L)-lactide under microwave irradiation with forward power of 255 W. A degradation of the Poly((D,L)-lactide) was also induced by microwaves with a power level over 340 W. The molar mass of Poly((D,L)-lactide) was dependent upon the competition between the polymerization of (D,L)-lactide and the degradation of the resulting polymer.

引用

页码：1402 / 1405

页数：4

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