New approaches to fluorinated ligands and their application in catalysis

被引：41

作者：

Chen, WP ^{[1
]}

Xu, LJ ^{[1
]}

Hu, YL ^{[1
]}

Osuna, AMB ^{[1
]}

Xiao, JL ^{[1
]}

机构：

[1] Univ Liverpool, Leverhulme Ctr Innovat Catalysis, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

TETRAHEDRON | 2002年 / 58卷 / 20期

基金：

英国工程与自然科学研究理事会;

关键词：

fluorinated ligands; fluorinated phosphines; fluorinated polymers; C-C coupling; fluorous catalysis; supercritical CO2;

D O I：

10.1016/S0040-4020(02)00213-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Simple and generic approaches to fluorous soluble ligands have been developed and applied to the synthesis of various fluorinated arylphosphines including polymeric ones. The utility of some of these ligands has been demonstrated in catalysis in supercritical CO2 (scCO(2)) and fluorous solvents. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

收藏

页码：3889 / 3899

页数：11

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