Palladium-Catalyzed Heteroannulation of [60]Fullerene with Anilides via C-H Bond Activation

被引：114

作者：

Zhu, Bo ^{[1
,2
]}

Wang, Guan-Wu ^{[1
,2
,3
]}

机构：

[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China

[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

[3] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 73000, Gansu, Peoples R China

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 19期

基金：

中国国家自然科学基金;

关键词：

FULLERENE-MIXED PEROXIDES; RADICAL REACTIONS; BUCKMINSTERFULLERENE C-60; REGIOSELECTIVE SYNTHESIS; MANGANESE(III) ACETATE; ROOM-TEMPERATURE; CARBONYL YLIDES; ORTHO-ARYLATION; CYCLOADDITION; DERIVATIVES;

D O I：

10.1021/ol901675t

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The palladium-catalyzed reaction of [60]fullerene with a variety of readily available anilides, initiated by C-H bond activation and followed by cyclization, afforded [60]fulleroindolines in a highly regioselective manner. A plausible reaction mechanism was proposed.

引用

页码：4334 / 4337

页数：4

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