Surface and optical properties of films grown by radio frequency nanocrystalline anatase titania reactive magnetron sputtering

被引:48
作者
Liu, FM [1 ]
Wang, TM [1 ]
机构
[1] Beijing Univ Aeronaut & Astronaut, Sch Sci, Ctr Mat Phys & Chem, Beijing 100083, Peoples R China
基金
中国国家自然科学基金;
关键词
nanocrystalline anatase TiO2 film; XRD; XPS; Raman spectra; optical properties;
D O I
10.1016/S0169-4332(02)00569-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nanocrystalline anatase TiO2 films were deposited on glass and silicon substrates by using radio frequency reactive magnetron sputtering. Microstructural and optical properties were characterized by using X-ray diffraction (XRD), X-ray photoemission spectroscopy (XPS), Raman spectra, optical absorption and photoluminescence (PL). XRD and Raman spectroscopy detected a nanocrystalline anatase titania films for input power at 250 W, for argon/oxygen ratio at 50 sccm/5.0 sccm and for substrate temperature at 500 degreesC. Visible broad widened photoluminescence peak is interpreted as the emission of self-trapped excitons localized on TiO6 octahedra. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:284 / 290
页数:7
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