Single-turnover intermolecular reaction between a FeIII-superoxide-CuI cytochrome c oxidase model and exogeneous Tyr244 mimics

被引：25

作者：

Collman, James P. ^{[1
]}

Decreau, Richard A. ^{[1
]}

Sunderland, Christopher J. ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem, Palo Alto, CA 94306 USA

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 37期

关键词：

D O I：

10.1039/b607277a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An Fe-III-superoxide-Cu-I cytochrome c oxidase model reacts intermolecularly with hindered phenols leading to phenoxyl radicals, as was observed in the enzyme and evidence for the formation of an Fe-IV-oxo is presented.

引用

页码：3894 / 3896

页数：3

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