Monomeric and dimeric V(III) complexes supported by organic amides

被引：11

作者：

Berno, P ^{[1
]}

Moore, M ^{[1
]}

Minhas, R ^{[1
]}

Gambarotta, S ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1996年 / 74卷 / 11期

关键词：

vanadium; trivalent; amide; borohydride; dinuclear;

D O I：

10.1139/v96-219

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of VCl3(THF)(3) with two equivalents of R(2)NLi(R=Cy,Me(3)Si) yielded the two corresponding complexes (Cy(2)N)(2)V(mu-Cl)(2)Li(THF)(2) (1) and [(Me(3)Si)(2)N]2VCl(THF) (2). both complexes decomposed in hot toluene. In the case of complex 1 the reaction led to dimerization and formation of the dimeric [(Cy(2)N)(2)V(mu-Cl)](2) (3). Reaction of 2 with NaBH4 yielded the unprecedented borohydride derivative [(me(3)Si)(2)N]V-2(BH4)(THF) (4). The structures of all the complexes were elucidated by X-ray analysis.

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页码：1930 / 1935

页数：6

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