Design of Ordered Mesoporous Composite Materials and Their Electrocatalytic Activities for Water Oxidation

被引：169

作者：

Grewe, Tobias ^{[1
]}

Deng, Xiaohui ^{[1
]}

Weidenthaler, Claudia ^{[1
]}

Schueth, Ferdi ^{[1
]}

Tueysuez, Harun ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

CHEMISTRY OF MATERIALS | 2013年 / 25卷 / 24期

关键词：

ordered mesoporous materials; nanocasting; mixed oxides; water oxidation; OXYNITRIDE TAON PHOTOANODE; HYDROGEN-PRODUCTION; OXYGEN REDUCTION; COBALT OXIDE; METAL-OXIDES; MCO2O4; M; SILICA; CO3O4; CATALYST; XPS;

D O I：

10.1021/cm403153u

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The controlled synthesis of a series of ordered mesoporous composite materials via solid-solid reaction of ordered mesoporous Co3O4 with various transition metal precursors is reported. This versatile methodology allows preparation of a range of composites with precisely controllable material compositions. The textural parameters of the heterostructured compounds are highly dependent on the oxidation state of the dopant. Electrocatalytic activities of the prepared materials were investigated as oxygen evolution catalysts for the electrolysis of water. Among the ordered mesoporous composite materials, Co3O4-CuCo2O4 shows a significant enhancement for electro-catalytic water splitting with a lower onset potential and higher current density. Following these results, a series of ordered mesoporous composite materials based on cobalt and copper oxides with different atomic ratios were prepared through a nanocasting route. Enhanced electrocatalytic performance was obtained for all composite samples in comparison with Co3O4.

引用

页码：4926 / 4935

页数：10

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