Diels-Alder reactivity of 1-alkoxyphenyl-3-trialkylsiloxy-1,3-dienes

被引：11

作者：

Adeva, M ^{[1
]}

Caballero, E ^{[1
]}

Garcia, F ^{[1
]}

Medarde, M ^{[1
]}

Sahagun, H ^{[1
]}

Tome, F ^{[1
]}

机构：

[1] UNIV SALAMANCA,FAC FARM,DEPT QUIM ORGAN & FARMACEUT,E-37007 SALAMANCA,SPAIN

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 39期

关键词：

D O I：

10.1016/S0040-4039(97)01588-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of 1-(3,4,5-trimethoxyphenyl)-3-trialkylsiloxy-1,3-butadienes and their Diels-Alder reaction with selected dienophiles at room temperature is described. These aryldienes are useful building blocks for the synthesis of natural and pharmacological active products, as has been shown by the preparation of a tetracyclic ketone needed for the synthesis of new anthracycline analogues. (C) 1997 Elsevier Science Ltd.

引用

页码：6893 / 6896

页数：4

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