Four-fold inclined interpenetrated and three-fold parallel interpenetrated hydrogen bond networks in 1,3,5-cyclohexanetricarboxylic acid hydrate and its molecular complex with 4,4′-bipyridine

被引：121

作者：

Bhogala, BR ^{[1
]}

Vishweshwar, P ^{[1
]}

Nangia, A ^{[1
]}

机构：

[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

来源：

CRYSTAL GROWTH & DESIGN | 2002年 / 2卷 / 05期

关键词：

D O I：

10.1021/cg025537y

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Crystallization of 1,3,5-cyclohexanetricarboxylic acid (CTA) from EtOH affords the 1:1 hydrate, CTA.H2O, with 4-fold inclined interpenetrated (6,3) hydrogen-bonded networks. Crystallization of CTA with 4 4'-bipyridine (bipy) furnishes the complex, CTA.bipy.H2O (2:3:1), that has 3-fold interweaving (6,3) networks with parallel interpenetration. The striking similarity of these hydrogen bond networks to those found in the crystal structure of trimesic acid and its complex with bipy suggests that such interpenetrated networks may be engineered using retrosynthetic strategies.

引用

页码：325 / 328

页数：4

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