Flame spray synthesis under a non-oxidizing atmosphere: Preparation of metallic bismuth nanoparticles and nanocrystalline bulk bismuth metal

被引：45

作者：

Grass, Robert N. ^{[1
]}

Stark, Wendelin J. ^{[1
]}

机构：

[1] ETH, Inst Chem & Bioengn, CH-8093 Zurich, Switzerland

来源：

JOURNAL OF NANOPARTICLE RESEARCH | 2006年 / 8卷 / 05期

关键词：

bismuth; metal nanoparticle; flame spray; reducing flame synthesis; nanocrystalline metal; combustion; nanoengineering;

D O I：

10.1007/s11051-006-9097-2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metallic bismuth nanoparticles of over 98% purity were prepared by a modified flame spray synthesis method in an inert atmosphere by oxygen-deficient combustion of a bismuth-carboxylate based precursor. The samples were characterized by X-ray diffraction, thermal analysis and scanning electron microscopy confirming the formation of pure, crystalline metallic bismuth nanoparticles. Compression of the as-prepared powder resulted in highly dense, nanocrystalline pills with strong electrical conductivity and bright metallic gloss.

引用

页码：729 / 736

页数：8

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