Polymers of intrinsic microporosity (PIMs): High free volume polymers for membrane applications

被引：88

作者：

Budd, Peter M. ^{[1
]}

McKeown, Neil B.

Fritsch, Detlev

机构：

[1] Univ Manchester, Sch Chem, Organ Mat Innovat Ctr, Manchester M13 9PL, Lancs, England

[2] Univ Cardiff Wales, Sch Chem, Cardiff CF10 3AT, Wales

[3] GKSS Forschungszentrum Geesthacht GmbH, Polymer Res Inst, D-21502 Geesthacht, Germany

来源：

MACROMOLECULAR SYMPOSIA | 2006年 / 245卷

关键词：

gas separation; membrane; microporous polymer; pervaporation;

D O I：

10.1002/masy.200651356

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We are developing new types of polymer - termed polymers of intrinsic microporosity (PIMs) - which in the solid state behave like molecular sieves. As pervaporation membranes, they show selectivity for organics over water. As gas separation membranes, they exhibit a remarkable combination of high permeability and good selectivity for gas pairs such as O-2/N-2.

引用

页码：403 / 405

页数：3

共 14 条

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[2] Gas separation membranes from polymers of intrinsic microporosity [J].

Budd, PM ;

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Budd, PM ;

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[4] Solution-processed, organophilic membrane derived from a polymer of intrinsic microporosity [J].

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Tattershall, CE ;

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ADVANCED MATERIALS, 2004, 16 (05) :456-+

[5] A nanoporous network polymer derived from hexaazatrinaphthylene with potential as an adsorbent and catalyst support [J].

Budd, PM ;

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JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (11) :2721-2726

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[8] Adsorption studies of a microporous phthalocyanine network polymer [J].

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LANGMUIR, 2006, 22 (09) :4225-4229

[9] Polymers of Intrinsic Microporosity (PIMs): Bridging the Void between Microporous and Polymeric Materials [J].

McKeown, NB ;

Budd, PM ;

Msayib, KJ ;

Ghanem, BS ;

Kingston, HJ ;

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CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (09) :2610-2620

[10] Towards polymer-based hydrogen storage materials: Engineering ultramicroporous cavities within polymers of intrinsic microporosity [J].

McKeown, NB ;

Ghanem, BS ;

Msayib, KJ ;

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Tan, S ;

Book, D ;

Langmi, HW ;

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (11) :1804-1807

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