Towards polymer-based hydrogen storage materials: Engineering ultramicroporous cavities within polymers of intrinsic microporosity

被引:388
作者
McKeown, NB [1 ]
Ghanem, BS
Msayib, KJ
Budd, PM
Tattershall, CE
Mahmood, K
Tan, S
Book, D
Langmi, HW
Walton, A
机构
[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, Wales
[2] Univ Manchester, Sch Chem, Organ Mat Innovat Ctr, Manchester M13 9PL, Lancs, England
[3] Univ Birmingham, Sch Engn, Dept Met & Mat, Birmingham B15 2TT, W Midlands, England
基金
英国工程与自然科学研究理事会;
关键词
hydrogen storage; microporous materials; nanostructures; polymers;
D O I
10.1002/anie.200504241
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) Three structurally diverse polymers of intrinsic microporosity reversibly adsorb significant quantities of hydrogen (1.4-1.7% by mass at 77 K) and represent the first examples of a new type of purely organic hydrogen storage material, which can be tailored to meet the specific requirements of hydrogen physisorption. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:1804 / 1807
页数:4
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