Synthesis of MoO3 nanostructures and their facile conversion to MoS2 fullerenes and nanotubes

被引：66

作者：

Therese, Helen A.

Zink, Nicole

Kolb, Ute

Tremel, Wolfgang

机构：

[1] Johannes Gutenberg Univ Mainz, Inst Anorgan Chem & Analyt Chem, D-55099 Mainz, Germany

[2] Johannes Gutenberg Univ Mainz, Inst Chem Phys, D-55099 Mainz, Germany

来源：

SOLID STATE SCIENCES | 2006年 / 8卷 / 10期

关键词：

MoO3; nanorods; thermolysis; MoS2; nanotubes; inorganic fullerene-like;

D O I：

10.1016/j.solidstatesciences.2006.05.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The fast thermolysis of ammonium molybdate leads to a mixture Of MoO3 and Mo5.3O14.5(OH)(2.8)(H2O)(1,36) with spherical and rod-like morphologies. The oxide mixture can be converted in quantitative yield to inorganic fullerene-type (IF) MoS2 and MoS2 nanotubes (NT) by H2S reduction using a facile and quick procedure. The products were studied by X-Ray Diffraction (XRD) and by Transmission Electron Microscopy (TEM). TEM analysis reveals that the spherical and rod-like morphology of the oxide precursor is preserved during the H2S treatment. (c) 2006 Elsevier Masson SAS. All rights reserved.

引用

页码：1133 / 1137

页数：5

共 32 条

[1]

ANDERSON G, 1988, ACTA CHEM SCAND, V1, P1973

[2] TiO2-B nanowires [J].