A novel 3D Mn(II) coordination polymer involving 4,4′-dipyridylsulfide and 4,4′-dipyridyltrisulfide obtained by in situ ligand formation from 4,4′-dipyridyldisulfide

被引：64

作者：

Ma, Lu-Fang ^{[1
]}

Wang, Li-Ya ^{[1
]}

Du, Miao ^{[2
]}

机构：

[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China

[2] Tianjin Normal Univ, Tianjin Key Lab Struct & Performance Funct Mol, Coll Chem & Life Sci, Tianjin 300387, Peoples R China

来源：

CRYSTENGCOMM | 2009年 / 11卷 / 12期

关键词：

HYDROTHERMAL SYNTHESIS; S-S; COMPLEXES; DECARBOXYLATION; FRAMEWORKS; NETWORKS; DISULFIDE; CHEMISTRY; INFINITE; CLEAVAGE;

D O I：

10.1039/b914827m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new coordination polymer, {[Mn(mip)(dps)](dpts)(0.5)}(2n) (1) (mip = 5-methylisophthalate) has been solvothermally synthesized by in situ generation of 4,4'-dipyridylsulfide (dps) and 4,4'-dipyridyltrisulfide (dpts) ligands from a 4,4'-dipyridyldisulfide (dpds) precursor. The coordination framework of 1 shows a new (3,5)-connected 3-D net topology with a Schlafli symbol of (4(2).6(5).8(3))(4(2).6), in which weak antiferromagnetic interactions are observed between the Mn-II ions.

引用

页码：2593 / 2596

页数：4

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