Solvothermal in situ ligand synthesis through disulfide cleavage: 3D (3,4)-connected and 2D square-grid-type coordination polymers

被引：135

作者：

Han, Lei

Bu, Xianhui

Zhang, Qichun

Feng, Pingyun ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

[2] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 15期

关键词：

D O I：

10.1021/ic0608041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel coordination polymers, Cu-3(4-pyt)(3) (1) and Co(4-pyt)(2) (2) (4-pyt = pyridine-4-thiolate), have been synthesized by in situ generation of a 4-pyt ligand from a 4,4'-dithiodipyridine precursor through reductive cleavage of the disulfide bond under solvothermal conditions. 1 and 2 exhibit a three-dimensional (3,4)-connected network and a two-dimensional square-grid-type structure, respectively.

引用

收藏

页码：5736 / 5738

页数：3

相关论文

共 36 条

[1] Syntheses, characterization and thermal properties of [M(Spy)2(SpyH)2] (M = Cd and Hg;: Spy- = pyridine-4-thiolate;: SpyH = pyridinium-4-thiolate)) and [M(SpyH)4](ClO4)2 (M = Zn, Cd and Hg) [J].

Anjali, KS ;

Vittal, JJ ;

Dean, PAW .

INORGANICA CHIMICA ACTA, 2003, 351 :79-88

[2] Templated assembly of sulfide nanoclusters into Cubic-C3N4 type framework [J].

Bu, XH ;

Zheng, NF ;

Li, YQ ;

Feng, PY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (20) :6024-6025

[3] Layered metal organosulfides:: hydrothermal synthesis, structure and magnetic behaviour of the spin-canted magnet Co(1,2-(O2C)(S)C6H4) [J].

Cave, D ;

Gascon, JM ;

Bond, AD ;

Teat, SJ ;

Wood, PT .

CHEMICAL COMMUNICATIONS, 2002, (10) :1050-1051

[4] Polymeric (μ2-nitrato-κ2O:O′)(μ2-nitrato-κ2O:O)(μ4-pyridinium-4-thiolato-κ4S:S:S:S)disilver(I) [J].

Chen, YB ;

Kang, Y ;

Qin, YY ;

Li, ZJ ;

Cheng, JK ;

Yao, YG .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 :M263-M265

[5] A 3-D noninterpenetrating diamondoid network of a decanuclear copper(I) complex [J].

Cheng, JK ;

Chen, YB ;

Wu, L ;

Zhang, J ;

Wen, YH ;

Li, ZJ ;

Yao, YG .

INORGANIC CHEMISTRY, 2005, 44 (10) :3386-3388

[6] A simultaneous redox, alkylation, self-assembly reaction under solvothermal conditions afforded a luminescent copper(I) chain polymer constructed of Cu3l4- and EtS-4-C5H4N+Et components (Et = CH3CH2) [J].

Cheng, JK ;

Yao, YG ;

Zhang, J ;

Li, ZJ ;

Cai, ZW ;

Zhang, XY ;

Chen, ZN ;

Chen, YB ;

Kang, Y ;

Qin, YY ;

Wen, YH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (25) :7796-7797

[7] Microporous manganese formate: A simple metal-organic porous material with high framework stability and highly selective gas sorption properties [J].

Dybtsev, DN ;

Chun, H ;

Yoon, SH ;

Kim, D ;

Kim, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (01) :32-33

[8] In2(OH)3(BDC)1.5 (BDC=1,4-benzendicarboxylate):: An In(III) supramolecular 3D framework with catalytic activity [J].

Gomez-Lor, B ;

Gutiérrez-Puebla, E ;

Iglesias, M ;

Monge, MA ;

Ruiz-Valero, C ;

Snejko, N .

INORGANIC CHEMISTRY, 2002, 41 (09) :2429-2432

[9] Red luminescent polymeric cuprous organosulfide generated by solvothermal redox reaction [J].

Han, L ;

Hong, MC ;

Wang, RH ;

Wu, BL ;

Xu, Y ;

Lou, BY ;

Lin, ZZ .

CHEMICAL COMMUNICATIONS, 2004, (22) :2578-2579

[10] Isolated magnetic clusters of Co(II) and Ni(II) within 3-dimensional organic frameworks of 6-mercaptonicotinic acid: Unique structural topologies based on selectivity for hard and soft coordination environments [J].

Humphrey, SM ;

Mole, RA ;

McPartlin, M ;

McInnes, EJL ;

Wood, PT .

INORGANIC CHEMISTRY, 2005, 44 (17) :5981-5983

← 1 2 3 4 →